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Could you please check the PBS Professional 13.0 Administrator guide:
4.8.2.2.ii Example of Associating Multiple Vnodes with Multiple Queues -
if you want to hard map the node(s) to a queue:
qmgr -c "set node NODENAME queue=QUEUENAME"
Caution: if you hard map node to a queue, then the node(s) will be dedicated to only that queue. Jobs from other
queue would not able to utilized the nodes hard mapped to this queue.